Rice's spokesperson confirmed the appearance to The Wrap, adding that the former Secretary of State had taped her appearance on the show in March.
Rice was named as one of Jack Donaghy's (Alec Baldwin) love interests in season one. In an episode titled "The Break Up," Donaghy keeps the affair a secret, but gets upset when he sees Rice with Vladimir Putin and they eventually broke up.
Rice was the first African-American Secretary of State and the second woman, after Madeleine Albright. Rice was also President George W. Bush's National Security Advisor during his first term. Before joining the Bush administration, she was a political science professor at Stanford University. She returned to Stanford in 2009 and became a faculty member at the Stanford Graduate School of Business and director of its Global Center for Business and the Economy in 2010.