He told dispatchers he thought she might have taken too much medication for anxiety or depression.
Officers who responded to the call found several prescription bottles, including Ambien and anti-anxiety medication, that had been filled within 10 days but were empty, according to a police report. It also said there was a handwritten note that indicated she had taken the pills intentionally.
The Kings filed for divorce in April, but Larry King released a statement through his spokesman, Howard Rubenstein, saying "reports that we have fought are absolutely false."
Shawn King is Larry King's seventh wife. The couple has been married since 1997 and has two sons.
The Associated Press contributed to this story.
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