Few details were immediately available about the shooting, which occurred in the late morning near the intersection of Locust Avenue and Mariposa Road, just east of the 15 Freeway.
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The deputies were responding to a report of the two collisions when they arrived at the scene and contacted the pedestrian, identified only as a man, according to the San Bernardino County Sheriff's Department.
In a statement provided to ABC7, a spokesperson for the agency said "a lethal force encounter occurred and the pedestrian was struck by gunfire."
The man was pronounced dead at the scene.
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The investigation was ongoing.