Ladd plays mom to Katherine Heigl, who plays a troubled woman who can't quite get over her divorce, especially when her ex-husband finds someone new.
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Things will get nasty, but for Ladd, being in this movie was a delight.
"She was such a delicious person to play," she said. "Lovey is such a deeply disturbed woman and yet she thinks she's the great mother on the planet."
Ladd also loved working opposite Heigl. She said it just clicked, and Heigl agreed.
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"She's just such a wonderful person to be around, which is so funny because she plays not such a nice person," Heigl said.
Ladd's TV past on "Charlie's Angels" produced a lifelong friendship with her co-star Jaclyn Smith. The two are working on a potential return to television with a whole different show.
"Unforgettable" is now in theaters.